石英尾砂对旱地表土磁性的影响及其环境意义   总被引：1，自引：0，他引：1  

李勇  李海燕 《现代地质》2008,22(5):889-894

对安徽省凤阳县石英尾砂、受尾砂影响的表土、旱地表土和城镇表土进行了磁学测量,结果表明这4类样品的磁性特征明显不同。尽管这4类样品的磁化率均由磁铁矿主导,但旱地表土中可能含少量磁赤铁矿,石英尾砂、受尾砂影响的表土和城镇表土中可能含少量铁的氢氧化物（如纤铁矿）,受尾砂影响的表土中还含少量赤铁矿。城镇表土中磁铁矿的含量明显高于其他3类样品,受尾砂影响的表土中的磁铁矿含量介于石英尾砂和旱地表土之间。城镇表土中磁铁矿的粒径范围较宽,小于1 μm,石英尾砂中磁铁矿的粒径大于0.1 μm,旱地表土中磁铁矿的粒径小于0.1 μm,受尾砂影响的表土中磁铁矿的粒径介于旱地表土与石英尾砂的粒径之间。城镇表土的磁化率与频率磁化率呈负相关,旱地表土的磁化率与频率磁化率呈正相关,而受石英尾砂影响的表土的磁化率与频率磁化率没有明显的相关关系。在城市工业和交通等人类活动的影响下,城镇表土的磁性较旱地表土增强。而在石英砂生产这一人类活动的影响下,受尾砂影响的表土的磁性较旱地表土减弱,这是由石英尾砂中磁性矿物的含量较旱地表土4的少所致。  相似文献   

赣中良山钼矿床流体包裹体特征及其地质意义     

沈滔  陈正乐  潘家永  韩凤彬  伍俊杰  吴玉  王永  周振菊 《现代地质》2016,30(1):17-28

良山钼矿是近年来赣中地区新发现的钼矿,浅部矿体主要赋存于南华系浅变质岩系的构造裂隙中,矿石类型以含辉钼矿石英脉为主。流体包裹体岩相学和显微测温结果表明：含辉钼矿石英脉中的流体包裹体主要呈星散状随机或成群分布,其形态多样,大小集中在2~15 μm,包裹体的类型主要有纯液相包裹体、富气相两相包裹体、富液相两相包裹体和含液体CO₂三相包裹体4类,其中以富液相两相包裹体最为发育;包裹体的均一温度为136~298 ℃,盐度为1.22%~10.11%NaCleqv,密度为0.78~0.99 g/cm3,成矿流体属中-低温、低盐度、较低密度流体;成矿压力估算为13~70 MPa,形成深度为0.5~2.6 km。流体包裹体激光拉曼光谱分析表明：包裹体中气液相成分以H₂O为主,气相中还有少量的CO₂和CO。H、O、S同位素组成显示：成矿流体的δD值介于-61‰~-57.9‰,δ¹⁸OH₂O值介于-3.32‰~-0.52‰,具有岩浆水和大气降水混合的特征;成矿热液中的δ³⁴S值介于-1.8‰~+1.9‰,具有岩浆硫的特征。综合成矿地质特征及相关分析,认为成矿流体可能与燕山期的岩浆活动有关,属于岩浆热液流体,混合作用及钾化作用是促进金属富集沉淀成矿的主要因素,推测矿床属于岩浆热液充填石英脉型钼矿。  相似文献   

栖霞市马家窑金矿床成矿流体地球化学特征   总被引：1，自引：0，他引：1  

胡伟华  邱介玲  程鑫  林永芸 《山东国土资源》2008,24(1):26-29

马家窑金矿床是胶东地区比较典型的石英脉型金矿床代表，属中低温热液矿床，成矿流体盐度较低，气相成分以H2O，CO2为主，其次是Na^＋，Ca^＋和Cl^-，K^＋和F^-较贫，流体的成分与大气降水热液相类似。成矿流体的H，O同位素值则反映大气降水在不同温度和不同水／岩值条件下与栖霞超单元回龙夼单元交换后的分布特征，认为马家窑金矿床的成矿热液属大气降水成因。  相似文献   

Cathodoluminescence imaging and titanium thermometry in metamorphic quartz     

F. S. SPEAR  D. A. WARK 《Journal of Metamorphic Geology》2009,27(3):187-205

Cathodoluminescence (CL) of quartz from metamorphic rocks representing a range of conditions from the garnet grade to the migmatite grade reveals a variety of textures, that is, a function of metamorphic grade and deformation history. Ti concentrations, determined by electron microprobe and ion microprobe, generally correlate with CL intensity (blue wavelengths), and application of the Ti‐in‐quartz thermometer (TitaniQ) reflects the temperature of quartz growth or recrystallization, and, in some settings, modification by diffusion. Quartz from garnet grade samples is not visibly zoned, records temperatures of 425–475 °C, and is interpreted to have recrystallized during fabric formation. Quartz grains from staurolite grade samples are zoned in CL with markedly darker cores and brighter rims, some of which are interpreted to have been produced by the dominant staurolite‐producing reaction, whereas others are interpreted as having formed by diffusion of Ti into quartz rims. Quartz from the matrix of kyanite and sillimanite grade samples are generally unzoned, although locally displays slightly brighter rims (higher Ti); quartz inclusions within garnet and staurolite have distinctly brighter rims, which are interpreted as having been produced by diffusive exchange with the host mineral. Quartz from migmatite grade samples displays highly variable CL intensity, which is dependent on the location of the grain. Matrix grains in melanosomes are largely unzoned or rarely zoned with darker cores. Leucosome quartz is strongly zoned with bright cores and dark rims and is interpreted as having formed during crystallization of the melt. Locally within the leucosome is observed oscillatory‐zoned quartz, which is interpreted as a subsolidus recrystallization to achieve strain relaxation. Quartz inclusions within garnet or plagioclase crystals often show bright domains separated by zones of dark CL. These enigmatic textures possibly reflect local melting fluxed by fluid inclusions. Temperatures calculated from the Ti–in–quartz thermometer are a function of the metamorphic grade of the sample, the textural setting of the quartz, the reaction history and the deformation history of the rock. The TitaniQ temperatures can be used to constrain the conditions at which various metamorphic processes have occurred.  相似文献   

Pressure-induced incipient amorphization of α-quartz and transition to coesite in an eclogite from Antarctica: a first record and some consequences     

R. PALMERI  M. L. FREZZOTTI  G. GODARD  R. J. DAVIES 《Journal of Metamorphic Geology》2009,27(9):685-705

Monocrystalline quartz inclusions in garnet and omphacite from various eclogite samples from the Lanterman Range (Northern Victoria Land, Antarctica) have been investigated by cathodoluminescence (CL), Raman spectroscopy and imaging, and in situ X‐ray (XR) microdiffraction using the synchrotron. A few inclusions, with a clear‐to‐opalescent lustre, show ‘anomalous’ Raman spectra characterized by weak α‐quartz modes, the broadening of the main α‐quartz peak at 465 cm^?1, and additional vibrations at 480–485, 520–523 and 608 cm^?1. CL and Raman imaging indicate that this ‘anomalous’α‐quartz occurs as relicts within ordinary α‐quartz, and that it was preserved in the internal parts of small quartz inclusions. XR diffraction circular patterns display irregular and broad α‐quartz spots, some of which show an anomalous d‐spacing tightening of ～2%. They also show some very weak, hazy clouds that have d‐spacing compatible with coesite but not with α‐quartz. Raman spectrometry and XR microdiffraction characterize the anomalies with respect to α‐quartz as (i) a pressure‐induced disordering and incipient amorphization, mainly revealed by the 480–485 and 608‐cm^?1 Raman bands, together with (ii) a lattice densification, evidenced by d‐spacing tightening; (iii) the cryptic development of coesite, 520–523 cm^?1 being the main Raman peak of coesite and (iv) Brazil micro‐twinning. This ‘anomalous’α‐quartz represents the first example of pressure‐induced incipient amorphization of a metastable phase in a crustal rock. This issue is really surprising because pressure‐induced amorphization of metastable α‐quartz, observed in impactites and known to occur between 15 and 32 GPa during ultrahigh‐pressure (UHP) experiments at room temperature, is in principle irrelevant under normal geological P–T conditions. A shock (due to a seism?) or a local overpressure at the inclusion scale (due to expansion mismatch between quartz and its host mineral) seem the only geological mechanisms that can produce such incipient amorphization in crustal rocks. This discovery throws new light on the modality of the quartz‐coesite transition and on the pressure regimes (non‐lithostatic v. lithostatic) during high‐pressure/UHP metamorphism. In particular, incipient amorphization of quartz could favour the quartz‐coesite transition, or allow the growth of metastable coesite, as already experimentally observed.  相似文献   

贵州碳酸盐岩红色风化壳次生石英的裂变径迹测年研究   总被引：12，自引：1，他引：11  

王世杰  刘秀明  张峰 《地球化学》2005,34(1):33-40

贵州位于青藏高原东南缘,由于缺乏沉积记录其新生代的地质演化历史还不很明晰,而广泛分布于云贵高原的碳酸盐岩红色风化壳可能蕴涵着重要的地质演化信息.本文对贵州多个原位碳酸盐岩红色风化壳中产出的晶体形态较好的石英进行了裂变径迹方法测年.结果显示,石英的裂变径迹年龄数据呈现出较大的变化范围,从 1 Ma到 25 Ma,且远远地小于其三叠纪和寒武纪的母岩年龄;结合贵州 25 Ma到 1 Ma的区域地质演化历史,裂变径迹年龄值可以排除石英来源于母岩碎屑、成岩过程的次生形成以及火山活动产生的热水沉淀或交代形成的可能性,而只能推断为该晶体形态较好的石英于碳酸盐岩风化作用产生的富硅流体中沉淀形成;各剖面石英的年龄值与新生代的青藏高原夷平期、华南红土期、贵州构造稳定期乃至世界范围内的风化气候期有着良好的对应关系,说明次生石英裂变径迹测年具有很好的可行性和可靠性.  相似文献   

Quartz resources in the Serra de Santa Helena formation,Brazil: A geochemical and technological study     

《Journal of South American Earth Sciences》2014

This study presents an evaluation of Brazilian quartz deposits of Corinto and Olhos D'água, in Minas Gerais State, as potential high purity raw material for the production of silica glass. Both deposits are part of the Serra de Santa Helena formation, which holds other quartz deposits. Several quartz samples from these mines were analyzed to evaluate their chemical purity, by determination of the content of trace elements by ICP-MS after acid digestion. The technological characteristics of the ores after flame-fusion into silica glass were evaluated according to their bubble generation and UV transparency. The results indicate that silica glass with chemistry suitable for crucible applications can be obtained from materials of both mines, and even optical grade silica glass can be manufactured using transparent ore from one of the mines. In addition, this work explores the trace elements composition of each mine, as well as their fluid inclusions, and characterizes the mines as being of hydrothermal origin. Small differences in the physical and chemical characteristics of quartz that could affect the technological behavior of the ores are related to the geological history of the mines and provide interesting insights regarding the exploration of other quartz resources within the same geological formation.  相似文献   

广西苍梧社垌石英脉型钨钼多金属矿床流体演化及来源示踪     

张志强  陈懋弘  莫建明  肖柳阳  黄智忠  罗军  区朝辉 《岩石学报》2014,30(1):281-291

广西苍梧社垌矿床是大瑶山隆起南侧新发现的一个大型斑岩-矽卡岩-石英脉型钨钼多金属矿床。本文重点对其中的石英脉型矿床进行了研究,依据脉体穿插关系及矿物共生组合将成矿过程划分为I石英-黄铁矿阶段、II石英-白钨矿-辉钼矿阶段、III石英-多金属硫化物阶段以及IV石英-方解石-萤石阶段,其中II和III阶段为主成矿阶段。从早到晚,均一温度逐渐下降(第一阶段550℃→370℃,第二阶段370℃→330℃,第三阶段330℃→210℃,第四阶段190℃→150℃),流体密度逐渐上升(0.61g/cm3→0.72g/cm3→0.82g/cm3→0.94g/cm3),盐度先升后降(第一阶段5.86%～8.55%NaCleqv,第二阶段4.49%～43%NaCleqv,第三阶段0.53%～46.37%NaCleqv,第四阶段0%～12.85%NaCleqv)。激光拉曼成分分析显示,社垌石英脉型矿床的成矿流体属于H2O-NaCl体系,但是该体系的流体成分在成矿前后发生了较大的变化,反映第I阶段以氧化环境为主,(II、III、)IV阶段则为还原环境。氢氧同位素研究显示成矿流体来自于岩浆水,后期大气降水的加入导致矿质发生沉淀。此外金属硫化物的δ34S组成(-3.8‰～+1.7‰)平均为-0.46‰,接近于零值,也表明为岩浆来源。引起矿质沉淀的主要原因是流体混合导致的温度下降等环境条件的改变。总体而言,社垌石英脉型钨钼多金属矿床的成矿流体主要来自岩浆热液,为中高温、中低盐度、低密度的NaCl-H2O流体体系,钨钼等多金属成矿与区内加里东期岩浆作用密切相关。  相似文献   

东昆仑东段东昆中构造带韧性剪切作用及其地质意义   总被引：2，自引：1，他引：1       下载免费PDF全文

李小兵裴先治  刘成军陈有炘李瑞保  李佐臣陈国超 魏刚锋 《中国地质》2014,41(2):419-436

东昆仑东段东昆中构造带经历了多期(次)构造事件,现今保留了复杂多样的构造样式。哈图沟、清水泉—塔妥和沟里等地区构造变形十分强烈,且发育有呈NWW-SEE展布的韧性剪切带。通过野外调研及显微构造研究,对东昆中构造带几何学、运动学及动力学等进行了分析,并通过费氏台和EBSD技术对其进行石英C轴组构分析后认为该剪切带为一压-扭性构造界面,且早期为左旋逆冲,晚期为右旋走滑,变形温度为400~550℃。对剪切带内的石英亚颗粒及动态重结晶粒度测量计算出研究区内韧性剪切带古应力值约为153.791 MPa。哈图沟牦牛山组变形砾岩(4个测点)有限应变测量结果显示,越靠近东昆中断裂带砾石Flinn指数、应变程度、罗德系数(绝对值)越大,且Flinn指数均大于1,属拉伸变形。结合区域地质资料,认为东昆仑东段东昆中韧性剪切带形成于晚海西—印支期。  相似文献   

内蒙古白乃庙金矿含金石英脉LA-ICP-MS锆石U-Pb测年及其地质意义     

冯晓曦  姚书振  段明  王佳营  曲凯  魏佳林  李光耀  朱强 《地质通报》2014,33(10):1492-1501

为了厘定内蒙古白乃庙金矿床的成矿时代,对矿区主要含金石英脉中热液蚀变锆石进行了LA-ICP-MS U-Pb测年。结果表明,锆石热液蚀变特征明显,具有清晰的核—幔—边结构,锆石核、幔均为岩浆锆石或变质锆石,热液蚀变增生边呈自形—半自形结构,Th/U值集中于0.2~0.5之间,测年数据为421.4~447.6Ma,认为金矿形成时代为志留纪。从区域成矿规律分析,初步认为白乃庙金矿床的形成与早古生代古亚洲板块向华北地块强烈俯冲引起的构造—岩浆活动密切相关。  相似文献